Wilson equation

[ˈwɪlsən ɪˈkweʒən][ˈwilsn iˈkweiʃən]

威尔逊方程

  • The calculated activity coefficients are correlated using Wilson equation or McCann equation .

    活度系数的计算值由 Wilson 方程或McCann方程给出。

  • The correlating preciseness of the new equation is better than Wilson equation and as good as three-parameter NRTL equation and the new equation also satisfies th conditions of phase splitting .

    关联精度和三参数的NRTL方程相当,优于 wilson 方程,并且新方程能满足产生相分裂的必要条件。

  • The vapor-liquid equilibrium data Were correlated by means of the Wilson equation using a damping nonlinear least-square method . Values of the Wilson coupling energy parameters were evaluated .

    对实测的汽-液相平衡数据,以 Wilson 方程数学 模型,用阻尼排线性最小二乘法进行了关联,得出了该二元系在恒压下的wilson能量配偶参数。

  • Extraction separation results of ethyl acetate-ethanol-water were simulated with wilson equation By triangle-matrix method . Reflux ratio et al .

    提出了复合萃取法分离乙酸乙酯乙醇水,采用三对 角距 阵法模拟 计算乙酸乙酯乙醇水分离结果;

  • A fairly satisfactory result was gained when the experimental data were used in correlation with Wilson Equation .

    Wilson 方程进行关联,获得比较满意的结果。

  • The VLE data have been tested for thermodynamics consistency and correlated satisfactorily with Wilson equation .

    实测数据符合热力学一致性,并采用 Wilson 方程关联获得满意的结果。

  • The binary interaction parameters of WILSON equation were determinated by single parameter method .

    采用单参数法确定 Wilson 方程中的模型参数;

  • The experimental data are correlated by Wilson equation multi-parameter Wilson equation and NRTL equation with fairly good agreements .

    分别用 Wilson 方程、多参数Wilson方程和NRTL方程进行关联,都获得比较满意的结果。

  • Wilson equation and NRTL equation are used for making thermodynamic correlations the fitting accuracy is satisfactory .

    并用 Wilson及NRTL方程进行了热力学关联,其拟合精度是令人满意的。

  • The VLE models of extractive distillation with ACN method and DMF method for separating C4 were set up respectively by using Wilson equation . In terms of the models the processes of separating C4 were optimized by the computer simulation software .

    分别建立了ACN法和DMF法分离C4的 Wilson 活度 系数模型,并运用计算机模拟软件对萃取精馏分离C4的流程进行优化。

  • In this thesis the thermodynamic properties of 24 binary Al-based liquid alloys are then fitted with Wilson equation and the regular solution model .

    随后利用 Wilson 方程和正规溶液模型对24个二元铝基液态合金体系的热力学性质进行了拟合。

  • The data were correlated by Wilson equation which led to satisfactory result .

    威尔逊 方程关联,得到了满意的结果。

  • Excess Gibbs free energy and excess enthalpy for binary system of α - pinene-pinane were correlated by the Wilson equation and calculated values were in good agreement with measured values . For α - pinene - pinane system the maximum excess enthalpy is 120.4790 J · mol-1 .

    根据 Wilson 方程对α-蒎烯-蒎烷体系的过量Gibbs自由能和超额焓进行了关联,计算值与实验值基本吻合,最大超额焓为120.4790J·mol-1。

  • The Wilson equation was adopted for the computations of activity coefficients .

    活度系数的计算选用 Wilson 方程

  • Prediction about Thermodynamic Properties of Components in Binary Aluminum - based Liquid Alloys with Wilson Equation

    Wilson 方程对二元铝基液态合金组元热力学性质的预测

  • UNIFAC equation is used to calculate the VLE data of o-xylene + styrene system and the parameters of Wilson equation are also estimated for this system .

    采用基团贡献法计算得邻二甲苯+苯乙烯二元体汽液相平衡数据,并进而确定了该体系的 Wilson 方程模型参数。

  • Comparison between those models indicated that correlation using the two parameter equation the three parameter equation and the h equation were good while the error of correlation using the Wilson equation were bigger relatively .

    对四种溶解度模型结果进行了比较,结果表明两参数模型、三参数模型和人h方程都能较好地关联实验结果,相对而言 Wilson 方程的关联结果误差较大。

  • In order to evaluate the suitability of this method for predictions these VLE systems were predicted by One-parameter Wilson equation too .

    为了评价内聚能密度法的适应性,也用单参数 Wilson 方程法对相同体系的数据作了预测。

  • Vapour-liquid equilibria for the binary systems of acetone-water hydrocyanic acid-acetone hydrocyanic acid-water were correlated with Wilson equation multiparametric Wilson equation and NRTL equation ;

    Wilson 方程、多参数wilson方程和NRTL方程对丙酮-水、氢氰酸-丙酮、氢氰酸-水二元体系的汽液平衡数据进行了关联;

  • Calculation of solid-liquid adsorption equilibrium with Wilson equation and homogeneous solution theory

    应用 Wilson 方程和均相溶液理论计算固液吸附平衡

  • The experimental data were tested for thermodynamic consistency and correlated satisfactorily with Wilson equation .

    实验数据通过了热力学一致性检验,用 Wilson 方程关联,获得较满意的结果。

  • The comparison of application of Wilson equation and regular solution model in the Al-based liquid alloys shows that the suitability of regular solution model is restricted because it is only fit for the systems in which the components has the approximate size and structure .

    Wilson 方程和正规溶液模型在二元及多元铝基液态合金体系中的比较研究表明:正规溶液模型因为原则上只适用于组元的分子大小和结构相近的体系,其适用范围受到了限制。

  • The results show that this model may be respectively reduced to the Flory-Huggins equation the Wilson equation and NRTL equation in solution thermodynamics under some special conditions and it can be verified by the Gibbs-Duhem equation and expresses the thermodynamic properties of partially miscible systems .

    结果表明:该模型在某些特殊条件下,可分别还原为溶液热力学的Flory-Huggins方程、 Wilson 方程和NRTL方程,并且能够满足Gibbs-Duhem方程,能够描述部分互溶体系的热力学性质。

  • The vapor-liquid and liquid-liquid equilibria are calculated with the modified Wilson equation 6 、 7 w_244 .

    该系统的汽液和液液相平衡关系的计算采用修正的 威尔逊 方程式〔5〕。

  • The results also show that Wilson equation and regular solution model are not suitable for the systems that had immiscible gaps in the liquid phases .

    对于存在液-液分层现象的体系, Wilson 方程和正规溶液模型的拟合效果都较差,都不适合于这类体系的热力学性质计算。

  • The activity coefficient of the liquid phase was correlated by the Wilson equation and satisfactory correlation result of the experimental data was obtained .

    Wilson活度系数 方程对实验数据进行了关联,取得了较好的结果。

  • As to the weak deviation systems they are fitted well with Wilson equation and regular solution model .

    相对来说, Wilson 方程优于正规溶液模型。

  • The application of Wilson equation on the thermodynamic properties of components in binary aluminum-based liquid alloys was described . The values of Wilson equation were also indicated .

    描述了Wilson方程在二元铝基液态合金各组元热力学性质计算中的应用,介绍了 Wilson 方程在热力学计算中的优势。

  • VLE prediction with Lennard-Jones potential energy and one-parameter Wilson Equation

    用兰纳-琼斯位能和单参数 Wilson 方程预测汽液平衡