DFT Studies on the Tetrazine Substituted by Six-membered C & N Heterocyclic Derivatives

六元氮杂环取代 四 嗪化合物的密度泛函理论研究

The tetrazine high-nitrogen energetic materials are new kinds of ones researched and reported widely at home and abroad in recent years . The part of them possesses high enthalpy of formation good thermal stability lower sensitivity and so on .

四 嗪 类高氮含能材料也是近年来国内外研究和报道较多的一种新型含能材料，部分具有生成焓高、热稳定性好和感度较低等特点。

The Synthesis of Azole and Tetrazine Compounds and Study on Corrosion Inhibition for Copper in NaHCO_3 Medium

唑类及 嗪 类化合物的合成及其在碳酸氢钠介质中对铜缓蚀性能的研究

The molecular structure shows that two amide groups locate at 1 and 4 positions respectively and the tetrazine ring itself shows a boat conformation .

结果表明，该化合物的两个酰胺基处于 S- 四 嗪环的1位， 而 四 嗪环本身呈船式构象。

Tetrazine ring is an energetic nitrogen hexa-heterocyclic group with nitrogen mass fraction of 68.3 % so it is a very effective structure unit in the design of high energetic insensitive materials .

四 嗪环是一种含氮质量分数达68.3%的六元氮杂环含能基团，是设计高能钝感含能材料中非常有效的结构单元；

The application of high nitrogen energetic compounds in solid propellant gas generant explosive and smoke agent are reviewed . These high nitrogen energetic compounds are composed of tetrazine tetrazole and furazan .

综述了 四 嗪、四唑和呋咱等高氮含能化合物在固体推进剂、气体发生剂、炸药、烟火药等中的应用。

Electrochemical studies also indicate the interactions between the tetrazine sensors and these electron-rich compounds .

电化学研究也表明这些 探针分子与富电子化合物之间 存在相互作用。

Progress in High-nitrogen Energetic Materials Derived from Tetrazine and Tetrazole

国外 四 嗪 四唑类高氮含能材料研究进展

Theoretical Studies on the Structures and Properties of High-nitrogen Heterocycle Compounds : Triazole and Tetrazine Derivatives

三唑和 四 嗪 类高氮杂环化合物结构和性能的量子 化学研究