Free radical is a group of one or more than one unpaired electrons stayed high energy excited state which molecule induced by physical or chemical factors produce .
自由基是由于分子在物理或化学因素作用下产生 含有一个或一个以上的 不 配对电子,处于一种 不 稳定的高能激发态。
There are B-H bond H-H bond and atom-molecular bond in BH + 4 and BH4 . There are four equivalent B-H bonds in BH-4 . In the case of BH4 there is an unpaired electron that occurs near the boron atom .
BH4+和BH4中都存在BH键、HH键和原子-分子键;而 BH4-中存在着四个相同的BH键;
All unpaired atom molecule and atomic group are called free radicals which exist in body widely .
凡是 具有 未 成对 电子的原子、分子或原子团都称为自由基,在体内分布广泛。
Literally a radical is a molecule that reacts easily with other chemicals because of an unpaired electron .
精确地说,因为有 孤电子,所以分子中的基团与其他化学物质反应更加容易。
Their unpaired electrons make the atoms behave like tiny permanent magnets that align with and strengthen an applied magnetic field .
它们的 未 成对电子使原子成为小型的永磁体,它们 沿 外磁场排列,并因此增强外磁场。
On the other hand the double helix DNA molecule with low symmetry has a lot of hanging bonds and the unpaired electrons of these hanging bonds may come into the π - electrons system .
另一方面DNA分子具有双螺旋结构,其对称性较低,分子中存在大量的悬挂键,这些悬挂键上的 未 成对电子也会进入π&电子系统。
Isolation of dorsal unpaired median ( DUM ) neurons from the central nervous system of the cockroach Periplaneta americana and patch-clamp recording of their voltage-gated sodium current
美洲大蠊中枢 DUM神经元的分离和电压门控Na~+电流的记录
So the only way I can get an unpaired is to put it alone in another orbital .
所以获得不 成对 电子的唯一方法是,把它放在另一个轨道上。
There is a EPR signal with the characteristics of delocalization unpaired electrons ;
有非定域化 不 成对电子特征的顺磁共振信号;
And what I want to point out that we just figured out for molecular orbital theory is that o2 is a biradical because remember the definition of a radical is when we have an unpaired electron .
我要指出的是,我们刚利用分子轨道理论,指导了O2是二价自由基,因为记住,自由基的定义是,有个未 配对的电子。
Because these things are unpaired we have already seen how unpaired electrons play a role in the Stern-Gerlach experiment .
因为它们都是 未 成对的,我们已经发现,在Stern-Gerlach实验中,未成对电子扮演怎样一个角色了。
According to the classification of free radicals the Character of the molecular orbital occupied by the unpaired electron was presented .
提出按 未 完成对电子 占据的分子轨道特性对自由基系统进行分类。
A free radical is a molecular fragment having an unpaired electron .
自由基是一种具有未 配对电子的分子碎体。
And I cannot have an unpaired electron in the same orbital .
我不可能在同一个轨道,得到 不 成对电子。
You can see that we have two unpaired electrons in this molecule here one in the pi2 p x star and one in the pi2 p y star orbital .
你们可以看到我们这个,分子力有两个 未 配对电子,一个在π2px星,一个在π2py星轨道。
So we can bring in four hydrogen atoms which will each contribute another unpaired electron .
我们可以引入4个氢原子,每个贡献一个 未 配对的电子。
Three unpaired electrons in nitrogen .
有三个 未 成 键电子在氮 原子中。
So now what we have is four unpaired electrons .
现在我们有4个 未 配对电子。
The results were analyzed with unpaired t test and correlativity test .
所有结果采用 非 配对t检验和相关性分析。
An atom or group of atoms with at least one unpaired electron .
至少含有一个 不 成对电子的原子或原子团。
But what we see we have is that we only have two unpaired electrons here .
但我们看到,我们只有两个 未 配对的电子。
The free radical theory of aging posits that substances with unpaired electrons attack the body 's molecules and cause the functional decline of organs over time .
衰老的自由基学说指出,自由基中的 不 配对电子攻击人体内其他物质的分子,从而进行 配对,引起器官功能衰退。
Free radicals develop when atoms in the body 's cells have unpaired electrons which can lead to damage to different parts of the cell including DNA .
自由基发生是当身体细胞中的原子有 单电子,能导致包括DNA在内的细胞不同部分的破坏。
And again we have the pairing of the unpaired electrons and we have two orbitals coming together .
同样,我们有 未 配对电子的配对,我们有两个轨道结合。
So using our simple valence bond theory what we would expect is that we want to pair up any unpaired electrons in methane with unpaired electrons from hydrogen and form bonds .
利用简单的价电子成键理论,我们预计,要把所有甲烷中 没有配对的电子,和氢原子中没有 配对的电子配对来形成键。
S & we don 't have to hybridize it it already has only one unpaired electron in a1 s orbital .
s-我们不用杂化它,它已经有而且仅有一个 未 配对电子在s轨道里。
H2 So the simplest case we can think of is with h2 where we have two unpaired electrons each in a1 s orbital of a separate h atom .
最容易想到的例子是2,我们有两个 未 配对电子,每个都在一个分开的1s轨道上。
These unpaired electrons are the cause for the high chemical reactivity of free radicals .
由于这些 不 配对电子,这些分子或原子常 具有高度的化学活性。
Electron spin resonance technique ( ESR ) is a type of magnetic resonance . It can be used to study on asymmetric electron system . An unpaired electron system also can be studied with self-rotate marking method for ESR technique .
电子自旋共振(ElectronSpinResonance,简称ESR)技术是磁共振技术的一种,它可以对不成对的电子体系进行研究,而且对于 不 成对电子体系,可以采用自旋标记技术进行ESR的研究。
美[ʌn'perd]英['ʌn'peəd]
adj.不成双的,无对手的