tautomerism

[tɔ:'tɒməˌrɪzəm][tɔ:'tɒmərɪzəm]

n.互变现象

  • And it is ascertained that there exists the tautomerism of in it .

    确定其存在着 互变 异构

  • INVESTIGATION OF HYDR AZO NE - AZO TAUTOMERISM OF PYRIDONE AZO DYESTUFFS I The Application of Nuclear Magnetic Resonance For Identification of the Configurations

    吡啶酮系偶氮染料腙式偶氮式 互变 异构的研究Ⅰ核磁共振波谱在构型测定中的应用

  • The Content Analysis of The Enol Form Tautomerism

    烯醇式 变异 的含量分析

  • The influence of tautomerism ( enol and keto ) of DKAs molecular field charge alignment rules and other factors on the CoMFA model were considered .

    在模型的构建过程中,考虑了二酮酸类化合物的 互变 异构 现象(酮式和烯醇式)、分子场、电荷以及叠合方式等因素对CoMFA模型的影响。

  • Theoretical Study on the Tautomerism of 1-3H Atom Transformation Reactions at the 3 N System Substituted by Halogen

    卤取代对三氮系1-3H原子转移 互变 异构影响的理论研究

  • It is an obvious feature that the detur groups always take place tautomerism in this process such as in the excited state enol form transfers to keto form and result in red-shift of the emission wavelength of molecules .

    在此过程中给质子基团往往会发生 互变 异构 现象,如烯醇在激发态时发生烯醇式向酮式转变的 互变 异构 现象,导致分子发射波长向长波长显著移动,这是ESIPT的一个重要特征。

  • Stereochemistry of tautomerism ⅰ . studies on tautomeric equilibrium of alkyl malonic esters

    互变 异构的立体化学Ⅰ.烃基丙二酸酯的互变异构平衡的研究

  • Theoretical Studies on Energetic Properties of Nitrogen Heterocyclic Compounds and Tautomerism of Cyameluric Acid

    氮杂环含能性质及 CyameluricAcid异构化的理论研究

  • The states of active hydrogens the hindered rotation within molecules and the kinetic phenomena of tautomerism have also been discussed .

    还对分子内的受阻旋转、活泼氢状态以及 变异 的动力学现象作了讨论。

  • Some molecular swich is using the tautomerism of molecular framwork this sometimes is the tunneling effect of electron or proton or hydrogen atoms .

    有的分子开关则是利用了分子的机构 互变 现象,而这往往也就是电子、质子、氢原子、甚至原子基团的隧穿现象。

  • The tautomerism of β - keto esters is a typical system of enol-keto tautomerism which has been thoroughly studied in liquid phase yet less in gas phase for lacking of effective techniques .

    β-二酮类化合物存在着互变异构现象,是典型的烯醇-酮互变体系。其溶液体系的 互变现象研究得比较透彻,而气相体系由于缺少研究手段,这方面的报道很少。

  • Progress in the Tautomerism and Decomposition of Amino-tetrazoles

    氨基四唑化合物 异构和分解反应的研究进展

  • The starting temperature of valence tautomerism is about 300 K.

    自旋 交叉和价态 互变 相变起始温度约300K。

  • It has been pointed out that the phenomenon of colour-change caused by acid-base is due to the shift of equilibrium in hydrazone-azo tautomerism according to the influence of pH values upon 13C chemical shifts 1H NMR spectra and UV-VIS absorption spectra .

    从pH值对~(13)C化学位移的影响,~1HNMR谱和紫外-可见吸收光谱,指出这类染料的酸-碱变色现象是由腙式和偶氮式 构型 互变平衡的移动引起的。

  • Ketone - enol tautomerism was observed .

    观测到了酮-烯醇 互变 异构 现象

  • Azo - hydr azo ne tautomerism of azo dye

    偶氮染料的偶氮-醌腙 互变 异构

  • Study on the Tautomerism of β - Keto Esters by Gas Chromatography

    气相色谱研究β-二酮酯化合物的 互变 异构

  • But the tautomerism of these activity thio derivatives molecular can exist in biology systems and the different tautomers have variable activity effects .

    这些衍生物活性分子在生物体中存在着 互变 异构 现象,不同的异构体有不同的生物活性,这些 异构 的相对稳定性和异构体之间的相互转变对其性质具有重要的影响。

  • Study on Intramolecular Hydrogen-Bonding and Keto-Enol Tautomerism of Some Asymmetrical β - Diketones by 1H NMR

    不对称β-二酮分子内氢键及酮-烯醇 互变 异构的~1HNMR研究

  • Ab initio Calculation and Monte Carlo Simulation on Tautomerism and Proton Transfer of 2-Hydroxyimidazole in Gas Phase and Water

    2-羟基咪唑在气相和水中的 异构 平衡和质子迁移的从头算计算和MonteCarlo模拟

  • Azo-Hydrazone Tautomerism and Its Prediction in Dye - molecular Designing

    偶氮&腙体 互变 异构及其在染料分子设计中的预报

  • Effect of Ethanol on the Tautomerism of Ethyl Acetoacetate in Supercritical Co_2

    乙醇对超临界CO2中乙酰乙酸乙酯 异构化 平衡的影响

  • The results indicated that the properties of tautomerism of DBM could be applied to characterize the microenvironment al property of organized media reveal the structural characteristics of micelle and determine the critical micelle concentration of surfactant .

    结果表明,用二苯甲酰甲烷的 酮醇 互变 异构性质能够表征有序介质的微环境性质,确定表面活性物质的临界胶束浓度。

  • Study on quantum chemistry of nitroalkane tautomerism

    硝基烷烃 互变 异构的量子化学研究

  • Computation researches of molecular simulation on the principle of producing tautomerism tio_2 nanometer crystal in hydrolytic-hydrothermal system

    水解-水热体系中同质 异构TiO2纳米晶生成机理的分子模拟研究

  • Quantum Chemical Studies on Tautomerism of Tetrazole

    四唑 异构 异构反应的量子化学研究

  • Rules of wavelength and intensity of the fluorescence in different pH medium were discovered . The correlation between the protonation tautomerism and luminescence characteristics of quinolone are studied . It is found that in pH 6-8 or 2-4 there are two luminescence species .

    发现了在不同pH介质中喹诺酮类药物的荧光波长和荧光强度的变化规律,并对喹诺酮类药物质子化作用及 互变 异构 现象与荧光性质的相关性进行了考察。