Kinetics of unimolecular reaction of cf_2hcl on W surface

CF 2HCI在金属钨表面上的 反应动力学

The results obtained show that these compounds undergo unimolecular first-order pyrolytic reaction via a six-center cyclic transition state . This kind of the reaction is controlled by migrating of the atom H 17 with positive charge .

结果表明反应是一个 H17带正电迁移引发的途经六元环过渡态的 单 分子热消除 反应。

Coherent Laser Control over the Unimolecular Reaction of CH_3I

激光相干控制CH3I 单 分子 反应的实验研究

A Computer Program for Tunneling in Unimolecular Thermal Reaction System in Chemical Kinetics-KANDE

化学动力学中 单 分子热 反应隧道效应计算程序KANDE

Fluorination of the chlorohydrocarbon is substitution nucleophilic unimolecular . This fluorinated reaction is decided by the stability of intermediate R + .

氯代烃的氟化是 单 分子亲核取代反应，其氟化 反应的进程决定于中间体R+稳定性。

The mechanisms of the hydrolysis were proposed to be unimolecular nucleophilic substitution and bimolecular nucleophilic substitution ( SN2 ) . On the Problem of Bimolecular Nucleophilic Substitution Reaction Sterochemistry

水解反应的可能机理是SNl和S N2.双分子亲核取代 反应立体化学问题释疑

The unimolecular decomposition and dehydrogenation of ethanol initiate the branched chain reaction and the3 isomers of radical C2H5O determine the direction of the reaction chain branching .

乙醇氧化经裂解反应、脱氢反应最终形成支链 反应，乙氧基 C2H5O的三种同分异构体在链分支中决定了链分支的进行方向。

A mechanism including both unimolecular and chain reaction channel has been proposed for the decomposition of 1 & dichloropropane .

本研究证实了链式通道的存在，阐明了 1二氯丙烷分解 反应 中 单 分子 反应通道和链式 反应通道 共存 的 反应机理。

Study on Tunneling Effect in the Chemical Kinetics I. Study on Tunneling in Thermal Unimolecular Reaction of Formaldehyde

化学动力学中隧道效应的研究Ⅰ.甲醛 单 分子热 反应中隧道效应的研究

The unimolecular reaction of CF_2HCl dissociation on platinum black has been studied . At higher pressure this reaction is zero order while at lower pressure it I first order . It implies that the reaction is a typical catalytic reaction .

本文研究了CF 2HCl在铂黑表面上的 单 分子 反应，在压力较高时为零级，压力较低时为一级，表明此反应为典型的催化反应。